The complex that can show optical activity is:
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The complex that can show optical activity is:
An organic compound [A], molecular formula was hydrolyzed with dilute sulphuricacid to give a carboxylic acid [B] and alcohol[C]. Oxidation of [C] with produced [B]. Which of the following structuresare not possible for [A]?
If the boiling point of is 373 K, the boiling point of will be :
In a molecule of pyrophosphoric acid, thenumber of and bonds moiety(ies) respectivey are:
It is true that:
Which of the following compounds produces an optically inactive compound on hydrogenation ?




Henry's constant (in kbar) for four gases and in water at is given below: α β γ δ 50 2 0.5(density of water at ) This table implies that :

Tyndall effect of observed when :
Thermal power plants can lead to :
The electronic spectrum of shows a single broad peak with a maximum at 20,300 cm . The crystal field stabilization energy (CFSE) of the complex ion, in kJ mol, is :
Aqua regia is used for dissolving noble metals (Au, Pt, etc). The gas evolved in this process is :
The Kjeldahl method of Nitrogen estimation fails for which of the following reaction products ?

The mechanism of reaction is given as : A student writes general characteristics based on the given mechanism as : (a) The reaction is favoured by weak nucleophiles (b) would be easily formed if the substituents are bulky (c) The reaction is accompained by recemization (d) The reaction is favoured by non-polar solvents. Which observations are correct?

Which one of the following compounds possesses the most acidic hydrogen ?



Glycerol is separated in soap industries by :
Of the species, NO, NO , NO , NO , the one with minimum bond strength is :
The atomic number of the element unnilennium is :
An acidic buffer is obtained on mixing :
Let and be the conductances (in ) measured for saturated aqueous solutions of and respectively, at a temperatureT. Which of the following is false?
The antifertility drug 'Novestrol" can react with :
The volume strength of 8.9 M solution calculated at 273 K and 1 atm is _____. (R=0.0821 L atm K mol) (rounded off to thenearest integer)
The mole fraction of glucose in anaqueous binary solution is The masspercentage of water in it, to the nearest integer,is _______.
The photoelectric current from Na (work function, ) is stopped by the output voltage of the cell The pH of aq. HCl required to stop thephotoelectric current from all other conditions remaining the same, is ______. (to the nearest integer). Given,
An element with molar mass forms a cubic unit cell with edge length . If its density is the radius of theelement is approximately ______ (to thenearest integer).
The total number of monohalogenated organic products in the following (including stereoisomers) reaction is _____.

A die is thrown two times and the sum of the scores appearing on the die is observed to be a multiple of Then the conditional probability that the score 4 has appeared atleast once is :
The lines and
The foot of the perpendicular drawn from thepoint (4,2,3) to the line joining the points(1,-2,3) and (1,1,0) lies on the plane :
A hyperbola having the transverse axis oflength has the same foci as that of the ellipse then this hyperbola does notpass through which of the following points?
The area (in sq. units) of the region is :
If the first term of an A.P. is 3 and the sum of its first 25 terms is equal to the sum of its next 15 terms, then the common difference of this A.P. is :
Let be a point on the parabola, and be the foot of the perpendicular drawn from on the axis of the parabola. A line is nowdrawn through the mid-point of parallelto its axis which meets the parabola at If they-intercept of the line is then :
For the frequency distribution: where and the standard deviation cannot be :
is equal to :
Consider the two sets: both the roots of are real and . Which of the following is not true?
If then :
The function, isincreasing for all x lying in :
The value of up to term up to term is equal to :
If then is equal to :
The solution curve of the differential equation, which passesthrough the point is :
If the number of integral terms in the expansionof is exactly then the least valueof is :
If and are the roots of the equation and and are the roots of the equation then is equal to:
Let denote the greatest integer . If for some then isequal to :
is equal to:
The proposition is equivalentto:
Let and If then is equal to _____.
If then the value of is ________.
The diameter of the circle, whose centre lies onthe line in the first quadrant and whichtouches both the lines and is ______.
The value of is equal to ______.
If then thegreatest common divisor of the least values of and is ______.
Using screw gauge of pitch and 50 divisions on its circular scale, the thickness of an object is measured. It should correctly be recorded as:
Model a torch battery of length to be made up of a thin cylindrical bar of radius 'a' and a concentric thin cylindrical shell of radius 'b' filled in between with an electrolyte of resistivity (see figure). If the battery is connected to a resistance of value the maximum Joule heating in will take place for:-

When the wavelength of radiation falling on a metal is changed from to the maximum kinetic energy of the photoelectrons becomes three times larger. The work function of the metal is close to :
Moment of inertia of a cylinder of mass M, length and radius about an axis passing through its centre and perpendicular to the axis of the cylinder is If such a cylinder is to be made for a given mass of material, the ratio L/R for it to have minimum possible I is :-
The magnetic field of a plane electromagnetic wave is Where is the speed of light. The corresponding electric field is:
A charged particle carrying charge is moving with velocity . If an external magnetic field of exists in the region where the particle is moving then the force on the particle is . The vector is :
A (rms) source is connected to a resistance of an inductance of and a capacitance of 10 F all in series. The time in which the resistance (heat capacity ) will get heated by . (assume no loss of heat to the surroundings) is close to :
In a radioactive material, fraction of active material remaining after time is The fraction that was remaining after is :
A balloon filled with helium and1.7 atm.) bursts. Immediately afterwards the expansion of helium can be considered as:
Pressure inside two soap bubbles are 1.01 and 1.02 atmosphere, respectively. The ratio of their volumes is :
A satellite is moving in a low nearly circular orbit around the earth. Its radius is roughly equal to that of the earth's radius By firing rockets attached to it, its speed is instantaneously increased in the direction of its motion so thatis become times larger. Due to this the farthest distance from the centre of the earth that the satellite reaches is value of is :
In the circuit shown in the figure, the total charge in and the voltage across capacitor is . Then the charge on capacitor is :

An elliptical loop having resistance of semi major axis a, and semi minor axis b is placed in a magnetic field as shown in the figure. If the loop is rotated about the x-axis with angular frequency the average power loss in the loop due to Joule heating is :

When a diode is forward biased, it has a voltage drop of . The safe limit of current through the diode is . If a battery of emf is used in the circuit, the value of minimum resistance to be connected in series with thediode so that the current does not exceed thesafe limit is :
A uniform thin rope of length and mass hangs vertically from a rigid support and a block of mass is attached to its free end. A transverse short wavetrain of wavelength is produced at the lower end of the rope. What is the wavelength of the wavetrain (in ) when it reaches the top of the rope?
A block of mass slides with velocity on a frictionless horizontal surfaceand collides with a uniform vertical rod andsticks to it as shown. The rod is pivoted about and swings as a result of the collision making angle before momentarily coming to rest. If the rod has mass and length the value of is approximately :(Take

In a Young's double slit experiment, light of is used to produce an interference pattern. When the distance between the slits is the angular width (in degree) of the fringes formed on the distance screen is close to :
Magnitude of magnetic field (in SI units) at thecentre of a hexagonal shape coil of side ,50 turns and carrying current I (Ampere) inunits of is :
Consider a gas of triatomic molecules. Themolecules are assumed to the triangular andmade of massless rigid rods whose vertices areoccupied by atoms. The internal energy of a mole of the gas at temperature is :

Two isolated conducting spheres and ofradius and have and charges, respectively, and are at a large distancefrom each other. They are now connected bya conducting wire. A long time after this is donethe charges on and are respectively:
A bakelite beaker has volume capacity of at . When it is partially filled with volume(at ) of mercury, it is found that the unfilledvolume of the beaker remains constant astemperature is varied. If and where is thecoefficient of volume expansion, then (in cc) is close to _____.
A cricket ball of mass is thrownvertically up by a bowling machine so that itrises to a maximum height of after leaving the machine. If the part pushing the ball applies a constant force on the ball and moveshorizontally a distance of whilelaunching the ball, the value of in is _______.
When a long glass capillary tube of radius is dipped in a liquid, the liquid rises to a heightof within it. If the contact angle betweenthe liquid and glass to close to the surface tension of the liquid, in milliNewton is (Give answerin closest integer) ______.
A person of mass is standing on the rim of a circular platform of mass rotating about its axis as 5 revolutions per minute (rpm). The person now starts moving towards the centre of the platform. What will be the rotational speed (in rpm) of the platform whenthe person reaches its centre ________.
An observer can see through a small hole onthe side of a jar (radius ) at a point atheight of from the bottom (see figure). The hole is at a height of When the jaris filled with a liquid up to a height of the same observer can see the edge at thebottom of the jar. If the refractive index of the liquid where is an integer, the value of is _______.
